Fluvial responses towards the tannery effluent: Tracing the anthropogenic foot-prints.

Tannery-effluent is one of the top-ranked hazardous waste which is generally discharged into the river. To study the fluvial response toward the tannery-effluents and to trace anthropogenic foot-prints in the fluvial-system, a suite of systematically collected sediment and water samples were analyzed for radioactive (226Ra, 232Th, and 40K) and non-radioactive elements (Al, Ti, Cr, Mn, Fe, Co, Ni, Cu, Zn, As, Cd, Sb, Hg, and Pb). Neutron activation analysis and atomic absorption spectroscopy were used for elemental analysis, whereas HPGe-gamma-detector was used for measuring the primordial-radionuclides. Ranges of Cr-abundances in sediment and water were 63-4373 µg.g-1 and 15.6-52.2 µg.L-1, respectively which were ∼4-14 times higher than the geological background. Radioactivity concentrations of 226Ra, 232Th, and 40K ranged from 17.7-48.5, 36.1-81.6, and 687-1041 Bq.kg-1, respectively which were significantly depleted in effluent discharge point. Hence, primordial-radionuclides were used as natural tracers for tracing anthropogenic foot-prints which were explained in terms of dilution effect, redox environment and differential geo-environmental events/characteristics. From statistical-approaches and geochemical reasoning, elemental sources and responses in fluvial system were explored. Surprisingly, ecological & radiological risks were reduced while sediment quality guideline-based ecotoxicity & water-mediated health risks were increased by the incorporation of tannery effluents. This study describes the sedimentary response toward the received tannery effluents which is particularly explored by the primordial radionuclides.

Metal(loid)s in tap-water from schools in central Bangladesh (Mirpur): Source apportionment, water quality, and health risks appraisals.

Considering the health risks originating from the exposure of metal(loid)s in tap-water and the concomitant vulnerability of school-going students, 25 composite tap water samples from different schools and colleges of central Bangladesh (Mirpur, Dhaka) were analyzed by atomic absorption spectroscopic technique. Elemental abundances of Na, Mg, K, Ca, Cr, Mn, Fe, Co, Ni, Zn, As, Cd, and Pb in the studied tap water samples varied from 4520 to 62250, 2760-29580, 210-3000, 15780-78130, 1.54-5.32, 7.00-196, 2.00-450, 0.04-1.45, 8.23-24.4, 0.10-813, 0.10-10.5, 0.002-0.212, and 1.55-15.8 µgL-1, respectively. Dissolved metal(loid)s' concentrations were mostly within the national and international threshold values with few exceptions which were also consistent with the entropy-based water quality assessment. Multivariate statistical approaches demonstrated that hydro-geochemical processes like water-rock interactions mostly govern the major elemental (Na, Mg, K, Ca) compositions in tap water. However, anthropogenic processes typically control the trace elemental compositions where supply pipeline scaling was identified as the major source. Cluster analysis on sampling sites separated two groups of schools and colleges depending on their establishment years where tap water from older schools and colleges possesses relatively higher levels of metal(loid)s. Hence, gradual pipeline scaling on a temporal scale augmented the metal(loid)s' concentrations in tap-water. In terms of non-carcinogenic health risks estimation, studied tap-water seems to be safe, whereas elemental abundances of Pb and As can cause carcinogenic risks to school-going people. However, progressive deterioration of water quality by pipeline scaling will be supposed to cause significant health risks in the future, for which preventative measures should be adopted.

Mechanism of arsenic enrichment and mobilization in groundwater from southeastern Bangladesh: Water quality and preliminary health risks assessment.

To understand the mechanistic pathway of arsenic (As) enrichment and mobilization in groundwater (southeastern Bangladesh) and to evaluate the water quality as well as associated health risks, a suite of systematically collected groundwater samples (depth: 17-61 m) were analyzed. Arsenic concentrations (µg L-1) in the groundwater samples were ranged from 6 to 581 with a mean value of 199 which is significantly higher than the recommended values. The assessment of water quality using entropy water quality index and irrigation water quality indices revealed that the groundwater in the studied region was not recommended for drinking and irrigation, respectively with few exceptions. Dominant water types in the studied area were Ca-Mg-HCO3, Na-HCO3, and Na-Cl types. Various forms of water-rock interactions, leaching of evaporates, and the confined nature of the aquifer mostly control the hydro-chemical parameters. Fe/Mn bound As are likely to be released in the aquifer through the dissolution of carbonate minerals of Fe/Mn while the higher degree of water-rock interaction and probable oxidation of organic materials helped to elevate As concentration. The probable longer residence time of groundwater guided by topographic slope and the neighboring clayey aquitard govern the As mobilization in the aquifer. Probabilistic health risk assessment revealed that groundwaters from the studied area can cause both non-carcinogenic and carcinogenic health risks.